Spectrofluorometric Probe Method for Examining Preferential Solvation in Binary Solvent Mixtures

Study of preferential solvation in binary solvent mixtures by the spectra-streak picosecond technique

Using the picosecond spectra-streak method we monitored the dynamics of preferential solvation of a charge-transfer dipole in binary mixtures of solvents strongly different in dielectric constant. The observed slow (0.25-l ns) spectra1 red-shift of the charge-transfer (exciplex) fluorescence is considered to be mainly due to the formation and the dielectric enrichment of the salvation shell aro...

Preferential Solvation of Fenofibrate in (Ethanol or Acetone) + Water Mixtures at 298.15 K

The aim of this communication was to expand the results of numerical analyses performed by Sun et al. on their experimental solubility of fenofibrate in aqueous mixtures of ethanol and acetone at 298.15 K, in terms of the evaluation of the preferential solvation of this compound by the organic solvents and water in the saturated mixtures based on the inverse Kirkwood-Buff integrals (IKBI). ...

Solvation effects in near-critical binary mixtures.

A Ginzburg-Landau theory is presented to investigate solvation effects in near-critical polar fluid binary mixtures. Concentration dependence of the dielectric constant gives rise to a shell region around a charged particle within which solvation occurs preferentially. As the critical point is approached, the concentration has a long-range Ornstein-Zernike tail representing strong critical elec...

Preferential solvation of p - nitrophenol in binary solvent mixtures A Dissertation Submitted for the partial fulfillment FOR THE DEGREE OF MASTER OF SCIENCE IN CHEMISTRY

Ion solvation in liquid mixtures: effects of solvent reorganization.

Using field-theoretic techniques, we study the solvation of salt ions in liquid mixtures, accounting for the permanent and induced dipole moments, as well as the molecular volume of the species. With no adjustable parameters, we predict solvation energies in both single-component liquids and binary liquid mixtures that are in excellent agreement with experimental data. Our study shows that the ...